Chemistry And Chemical Reactivity

  chemistry and chemical reactivity: Chemistry & Chemical Reactivity John C. Kotz, Paul Treichel, Patrick A. Harman, 2003 Provides a broad overview of the principles of chemistry, the reactivity of chemical elements and their compounds, and the applications of chemistry. Conveys a sense of chemistry as a field that not only has a lively history but also one that is currently dynamic, with important new developments on the horizon
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity John C. Kotz, Paul M. Treichel, John Townsend, David A. Treichel, 2014-02-14 Reflecting Cengage Learning's commitment to offering flexible teaching solutions and value for students and instructors, this new hybrid version features the instructional presentation found in the printed text while delivering all the end-of chapter exercises online in OWLv2, the leading online learning system for chemistry. The result--a briefer printed text that engages learners online! Improve your grades and understanding of concepts with this value-packed Hybrid Edition. An access code to OWLv2 with MindTap Reader is included with the text, providing powerful online resources that include tutorials, simulations, randomized homework questions, videos, a complete interactive electronic version of the textbook, and more! Succeed in chemistry with the clear explanations, problem-solving strategies, and dynamic study tools of CHEMISTRY & CHEMICAL REACTIVITY, 9th edition. Combining thorough instruction with the powerful multimedia tools you need to develop a deeper understanding of general chemistry concepts, the text emphasizes the visual nature of chemistry, illustrating the close interrelationship of the macroscopic, symbolic, and particulate levels of chemistry. The art program illustrates each of these levels in engaging detail--and is fully integrated with key media components.
  chemistry and chemical reactivity: Chemistry & Chemical Reactivity John C. Kotz, Paul Treichel, Gabriela C. Weaver, 2006 Chapter Goals and Chapter Goals Revisited are two new features in this revision. Each chapter starts with a list of goals that allows students to see what is ahead. The chapter concludes with a repetition of that list with summary information added. General ChemistryNow is correlated to this list. New to this edition are dozens of Active Figures to help students visualize chemistry in action. These animated versions of text art help students master key concepts from the book. Active Figures can be used as demonstrations in the classroom and each figure is paired with a guided exploration and exercise to ensure students understand the concept being illustrated. In-text worked Examples follow a four-part structure: Problem statement, Strategy for approaching the problem, fully worked Solution, and, where appropriate, a Comment on the problem and solution. Through this approach, students learn how to approach a problem rather than merely learning to memorize problem types and memorized solution approaches. Exercises appear throughout the text so students can check their comprehension of the material. Answers are in an appendix. Problem-Solving Tips provide readers tips for determining how to approach and solve problems. Chemical Perspectives are essays that bring relevance and perspective to a study of chemistry. In order to put chemistry in its historical context, Historical Perspective essays describe the people who were key to developing the concepts of the chapter. A Closer Look essays describe ideas that form the background to material under discussion or provide another dimension of the subject. - Publisher.
  chemistry and chemical reactivity: Chemical Structure and Reactivity James Keeler, Peter Wothers, 2013-11 Chemical Structure and Reactivity: An Integrated Approach rises to the challenge of depicting the reality of chemistry. Offering a fresh approach, it depicts the subject as a seamless discipline, showing how organic, inorganic, and physical concepts can be blended together to achieve the common goal of understanding chemical systems.
  chemistry and chemical reactivity: Chemistry & Chemical Reactivity John C. Kotz, Paul Treichel, John Raymond Townsend, David A. Treichel, 2014-07-22 Succeed in chemistry with the clear explanations, problem-solving strategies, and dynamic study tools of CHEMISTRY & CHEMICAL REACTIVITY, 9e. Combining thorough instruction with the powerful multimedia tools you need to develop a deeper understanding of general chemistry concepts, the text emphasizes the visual nature of chemistry, illustrating the close interrelationship of the macroscopic, symbolic, and particulate levels of chemistry. The art program illustrates each of these levels in engaging detail--and is fully integrated with key media components. In addition access to OWLv2 may be purchased separately or at a special price if packaged with this text. OWLv2 is an online homework and tutorial system that helps you maximize your study time and improve your success in the course. OWLv2 includes an interactive eBook, as well as hundreds of guided simulations, animations, and video clips.
  chemistry and chemical reactivity: Chemical Reactivity Theory Pratim Kumar Chattaraj, 2009-02-23 In the 1970s, Density Functional Theory (DFT) was borrowed from physics and adapted to chemistry by a handful of visionaries. Now chemical DFT is a diverse and rapidly growing field, its progress fueled by numerous developing practical descriptors that make DFT as useful as it is vast. With 34 chapters written by 65 eminent scientists from 13 diffe
  chemistry and chemical reactivity: Chemical Kinetics Luis Arnaut, Hugh Burrows, 2006-12-21 Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses.* Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations* Of special interest to Industrial Chemistry and Biochemistry
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity John C. Kotz, 2011
  chemistry and chemical reactivity: Chemical Reactivity Savas Kaya, Laszlo von Szentpaly, Goncagul Serdaroglu, Lei Guo, 2023-05-26 The growth of technology for chemical assessment has led to great developments in the investigation of chemical reactivity in recent years, but key information is often dispersed across many different research fields. Combining both original principles and the cutting-edge theories used in chemical reactivity analysis, Chemical Reactivity, Volume 1 present the latest developments in theoretical chemistry and its application for the assessment of chemical processes. Beginning with an exploration of different theories and principles relating to electronic structure and reactivity of confined electronic systems, the book goes on to highlight key information on such topics as Dyson orbitals, target-ion overlaps, reaction fragility, magnetizability principles and the Fuki function. Density Functional Theory is discussed in relation to numerous different principles and approaches, with further information on constrained methods and diabatic models, bonding evolution theory, orbital-based population analysis models and charge transfer models, and Quantum chemistry and QTAIM. Consolidating the knowledge of a global team of experts in the field, Chemical Reactivity, Volume 1: Theories and Principles is a useful resource for both students and researchers interested in gaining greater understanding of the principles and theories underpinning chemical reactivity analysis. Provides readers with the key information needed to gain a good overview of contemporary chemical reactivity studies and a clear understanding of the theory behind state-of-the-art methods in the field Highlights advances in the computational descriptions of reactivity, including reactivity in confined environments, conceptual density functional theory, and multi-reference quantum chemistry Provides comprehensive coverage by consolidating the knowledge of many well-known researchers in the field from around the world
  chemistry and chemical reactivity: Chemistry Peter G. Mahaffy, Bob Bucat, Roy Tasker, Paul M. Treichel, John C. Kotz, Gabriela C. Weaver, John McMurry, 2014-03-10 Taking an evidence-first big picture approach, Chemistry: Human Activity, Chemical Reactivity encourages students to think like a chemist, develop critical understanding of what chemistry is, why it is important and how chemists arrive at their discoveries. Flipping the traditional model of presenting facts and building to applications, this text begins with contexts that are real-life and matter to students – from doping in sports, to the chemistry behind the treads of wall-climbing robots. Informed by the latest chemical education research, Chemistry: Human Activity, Chemical Reactivity presents chemistry as the exciting, developing human activity that it is, rather than a body of facts, theories, and skills handed down from the past. Along with the innovative MindTap Reader and OWLv2 learning platform, this text uses unique case studies and critically acclaimed interactive e-resources to help students learn chemistry and how it is helping to address global challenges of the 21st century.
  chemistry and chemical reactivity: Solvent Effects and Chemical Reactivity Orlando Tapia, Juan Bertrán, 2003-07-31 This book presents an up-to-date view of theories, practical methods and applications of solvent effects and chemical reactivity in condensed phases. Subjects treated include continuum solvation models, the theoretical basis for the treatment of solvent effects in density functional theory, Monte Carlo simulations of chemical reactions in solution, DFT molecular dynamics simulations, crossing the transition state in solution, valence bond multi-state approach to chemical reactions in solution, quantum theory of solvent effects and chemical reactions. The approaches taken as well as the resulting findings are discussed in detail, thus covering a large part of the methodology currently used in this field. Audience: This volume will be useful to graduate students in chemistry, physical chemistry and biochemistry, to research workers with a background in quantum chemistry and quantum mechanics, to pure and applied quantum chemists, and to industrial molecular modellers.
  chemistry and chemical reactivity: Theoretical Aspects of Chemical Reactivity , 2006-11-14 Theoretical Aspects of Chemical Reactivity provides a broad overview of recent theoretical and computational advancements in the field of chemical reactivity. Contributions have been made by a number of leaders in the field covering theoretical developments to applications in molecular systems and clusters. With an increase in the use of reactivity descriptors, and fundamental theoretical aspects becoming more challenging, this volume serves as an interesting overview where traditional concepts are revisited and explored from new viewpoints, and new varieties of reactivity descriptors are proposed. Includes applications in the frontiers of reactivity principles, and introduces dynamic and statistical viewpoints to chemical reactivity and challenging traditional concepts such as aromaticity. * Written by specialists in the field of chemical reactivity* An authoritative overview of the research and progress * An essential reference material for students
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity Kotz, 2012
  chemistry and chemical reactivity: Molecular Reaction Dynamics Raphael D. Levine, 2009-06-04 Molecular reaction dynamics is the study of chemical and physical transformations of matter at the molecular level. The understanding of how chemical reactions occur and how to control them is fundamental to chemists and interdisciplinary areas such as materials and nanoscience, rational drug design, environmental and astrochemistry. This book provides a thorough foundation to this area. The first half is introductory, detailing experimental techniques for initiating and probing reaction dynamics and the essential insights that have been gained. The second part explores key areas including photoselective chemistry, stereochemistry, chemical reactions in real time and chemical reaction dynamics in solutions and interfaces. Typical of the new challenges are molecular machines, enzyme action and molecular control. With problem sets included, this book is suitable for advanced undergraduate and graduate students, as well as being supplementary to chemical kinetics, physical chemistry, biophysics and materials science courses, and as a primer for practising scientists.
  chemistry and chemical reactivity: Why Chemical Reactions Happen James Keeler, Peter Wothers, 2003-03-27 This supplemental text for a freshman chemistry course explains the formation of ionic bonds in solids and the formation of covalent bonds in atoms and molecules, then identifies the factors that control the rates of reactions and describes more complicated types of bonding. Annotation (c)2003 Book News, Inc., Portland, OR (booknews.com).
  chemistry and chemical reactivity: Chemistry & Chemical Reactivity John C. Kotz, Paul Treichel, Gabriela C. Weaver, 2006 Chapter Goals and Chapter Goals Revisited are two new features in this revision. Each chapter starts with a list of goals that allows students to see what is ahead. The chapter concludes with a repetition of that list with summary information added. General ChemistryNow is correlated to this list. New to this edition are dozens of Active Figures to help students visualize chemistry in action. These animated versions of text art help students master key concepts from the book. Active Figures can be used as demonstrations in the classroom and each figure is paired with a guided exploration and exercise to ensure students understand the concept being illustrated. In-text worked Examples follow a four-part structure: Problem statement, Strategy for approaching the problem, fully worked Solution, and, where appropriate, a Comment on the problem and solution. Through this approach, students learn how to approach a problem rather than merely learning to memorize problem types and memorized solution approaches. Exercises appear throughout the text so students can check their comprehension of the material. Answers are in an appendix. Problem-Solving Tips provide readers tips for determining how to approach and solve problems. Chemical Perspectives are essays that bring relevance and perspective to a study of chemistry. In order to put chemistry in its historical context, Historical Perspective essays describe the people who were key to developing the concepts of the chapter. A Closer Look essays describe ideas that form the background to material under discussion or provide another dimension of the subject. - Publisher.
  chemistry and chemical reactivity: Effects of Electric Fields on Structure and Reactivity Sason Shaik, Thijs Stuyver, 2021-03-05 Electric-field-mediated chemistry is an emerging topic that is rapidly growing and fanning out in many directions. It involves theoretical and experimental aspects, as well as intense interplay between them, including breakthrough achievements such as the proof-of-principle that a Diels–Alder reaction, which involves two simultaneous C–C bond making events, can be catalysed or inhibited simply by changing the direction of an oriented external-electric field (OEEF). This productive interplay between the theoretical and experimental branches of chemistry is continuing, and gradually defining a new sub-field wherein various sources of electric fields, whether external or built-in and designed, or even surface induced fields (plasmons), are brought to bear on chemical reactions, molecular structures, and nano-systems, leading to control of reactivity, selectivity, chirality, molecular orientations, changes in structure, and in dynamics. Written by leaders in the field, Effects of Electric Fields on Structure and Reactivity is the first book on this exciting topic. Starting with an overview of the theory behind – and demonstrations of the effect of – electric fields on structure and reactivity, this accessible reference work aims to encourage those new to the field to consider harnessing these effects in their own work. Covering applications and recent theoretical developments, it is a useful resource for theoretical chemists and experimentalists alike.
  chemistry and chemical reactivity: Chemistry & Chemical Reactivity John C. Kotz, Paul M. Treichel, John Townsend, David Treichel, 2018-02-08 Help your students succeed in chemistry with the clear explanations, problem-solving strategies, and dynamic study tools of CHEMISTRY & CHEMICAL REACTIVITY, Tenth Edition. Recognized as one of the most progressive and engaging General Chemistry texts in the market, Kotz, Treichel, Townsend and Treichel help students develop a deeper understanding of general chemistry concepts.The text emphasizes the visual nature of chemistry, illustrating the close interrelationship of the macroscopic, symbolic, and particulate levels of chemistry with an art program that illustrates each of these levels in engaging detail. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity Michael J. Moran, John Townsend, 2011-05-24 With learning tools explicitly linked to the goals introduced in each chapter, this guide helps ensure that you are well prepared for class and exams. It includes chapter overviews, key terms with definitions, expanded commentary and study tips, worked-out examples, and direct references back to the text.
  chemistry and chemical reactivity: Chemical Waves and Patterns Raymond Kapral, K. Showalter, 2012-12-06 The concept of macroscopic waves and patterns developing from chemical reaction coupling with diffusion was presented, apparently for the first time, at the Main Meeting of the Deutsche Bunsengesellschaft fur Angewandte Physikalische Chemie, held in Dresden, Germany from May 21 to 24, 1906. Robert Luther, Director of the Physical Chemistry Laboratory in Leipzig, read his paper on the discovery and analysis of propagating reaction-diffusion fronts in autocatalytic chemical reactions [1, 2]. He presented an equation for the velocity of these new waves, V = a(KDC)1/2, and asserted that they might have features in common with propagating action potentials in nerve cell axons. During the discussion period, a skeptic in the audience voiced his objections to this notion. It was none other than the great physical chemist Walther Nernst, who believed that nerve impulse propagation was far too rapid to be akin to the propagating fronts. He was also not willing to accept Luther's wave velocity equation without a derivation. Luther stood his ground, saying his equation was a simple consequence of the corresponding differential equation. He described several different autocatalytic reactions that exhibit propagating fronts (recommending gelling the solution to prevent convection) and even presented a demonstration: the autocatalytic permanganate oxidation of oxalate was carried out in a test tube with the image of the front projected onto a screen for the audience.
  chemistry and chemical reactivity: Organic Chemistry Pierre Vogel, Kendall N. Houk, 2019-10-07 Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry is essential for achieving successful chemical reactions in organic chemistry. Chemists must be competent in a range of areas to understand organic synthesis. Organic Chemistry provides the methods, models, and tools necessary to fully comprehend organic reactions. Written by two internationally recognized experts in the field, this much-needed textbook fills a gap in current literature on physical organic chemistry. Rigorous yet straightforward chapters first examine chemical equilibria, thermodynamics, reaction rates and mechanisms, and molecular orbital theory, providing readers with a strong foundation in physical organic chemistry. Subsequent chapters demonstrate various reactions involving organic, organometallic, and biochemical reactants and catalysts. Throughout the text, numerous questions and exercises, over 800 in total, help readers strengthen their comprehension of the subject and highlight key points of learning. The companion Organic Chemistry Workbook contains complete references and answers to every question in this text. A much-needed resource for students and working chemists alike, this text: -Presents models that establish if a reaction is possible, estimate how long it will take, and determine its properties -Describes reactions with broad practical value in synthesis and biology, such as C-C-coupling reactions, pericyclic reactions, and catalytic reactions -Enables readers to plan chemical reactions more efficiently -Features clear illustrations, figures, and tables -With a Foreword by Nobel Prize Laureate Robert H. Grubbs Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis is an ideal textbook for students and instructors of chemistry, and a valuable work of reference for organic chemists, physical chemists, and chemical engineers.
  chemistry and chemical reactivity: Chemistry 2e Paul Flowers, Richard Langely, William R. Robinson, Klaus Hellmut Theopold, 2019-02-14 Chemistry 2e is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world applications, designed to enhance student learning. The second edition has been revised to incorporate clearer, more current, and more dynamic explanations, while maintaining the same organization as the first edition. Substantial improvements have been made in the figures, illustrations, and example exercises that support the text narrative. Changes made in Chemistry 2e are described in the preface to help instructors transition to the second edition.
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity, Enhanced Review Edition John Kotz, Paul Treichel, Gabriela Weaver, 2006-03-13 Kotz/Treichel/Weaver's Chemistry and Chemical Reactivity, Sixth Enhanced Review Edition includes unique Let's Review sections that are designed to help students prepare for multiple chapter exams. These new sections provide additional questions, including molecular and applied problems, linked to chapter goals and corresponding media resources. The Enhanced Review Edition is softbound and less expensive than the standard textbook. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.
  chemistry and chemical reactivity: Student Solutions Manual for Chemistry & Chemical Reactivity John C. Kotz, Paul M. Treichel, John Townsend, David Treichel, 2023-08-25 This useful manual contains fully worked-out solutions to all of the blue-numbered exercises in the text, giving you a way to check your answers and be sure you took the correct steps to arrive there.
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity, Volume 1 John Kotz, Paul Treichel, John Townsend, 2008-01-29 Chapters 1 -11 of the core text, including appendices. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.
  chemistry and chemical reactivity: Study Guide : Chemistry John C. Kotz, Harry E. Pence, Alton J. Banks, Keith F. Purcell, 1991
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity John C. Kotz, Paul M. Treichel, John Townsend, David Treichel, 2018
  chemistry and chemical reactivity: Bretherick's Handbook of Reactive Chemical Hazards L. Bretherick, 2016-10-27 Bretherick's Handbook of Reactive Chemical Hazards, Fourth Edition, has been prepared and revised to give access to a wide and up-to-date selection of documented information to research students, practicing chemists, safety officers, and others concerned with the safe handling and use of reactive chemicals. This will allow ready assessment of the likely potential for reaction hazards which may be associated with an existing or proposed chemical compound or reaction system. A secondary, longer-term purpose is to present the information in a way which will, as far as possible, bring out the causes of, and interrelationships between, apparently disconnected facts and incidents. This handbook includes all information which had become available to the author by April 1989 on the reactivity hazards of individual elements or compounds, either alone or in combination. It begins with an introductory chapter that provides an overview of the complex subject of reactive chemical hazards, drawing attention to the underlying principles and to some practical aspects of minimizing such hazards. This is followed by two sections: Section 1 provides detailed information on the hazardous properties of individual chemicals, either alone or in combination with other compounds; the entries in Section 2 are of two distinct types. The first type of entry gives general information on the hazardous behavior of some recognizably discrete classes or groups of the 4,600 or so individual compounds for which details are given in Section 1. The second type of entry concerns reactive hazard topics, techniques, or incidents which have a common theme or pattern of behavior involving compounds of several different groups, so that no common structural feature exists for the compounds involved.
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity John Kotz, Paul Treichel, John Townsend, 2008-02-07 CHEMISTRY & CHEMICAL REACTIVITY, 7e, combines thorough instruction with powerful multimedia tools to give you a deeper understanding of general chemistry concepts. The book has a long-standing reputation for logical organization; macro to micro orientation; a superior art program; and state-of-the art media, which is expanded in the new edition. The text clearly emphasizes the visual nature of chemistry and illustrates the close interrelationship of the macroscopic, symbolic, and particulate levels of chemistry. With clear writing, seamless technology integration, and robust homework/assessment tools, CHEMISTRY & CHEMICAL REACTIVITY, 7e, equips you with tools to empower the mastery, assignment, and assessment of chemical principles. The text's art program reveals these three levels in engaging detail--and is fully integrated with new key media components. The Web-based tutorial CengageNOWTM generates a personalized study plan to meet your specific needs and includes Go Chemistry mini video lectures and flash cards that offer the perfect quick review for students on the go. Fully customizable OWL is a Web-based homework system that maximizes study time and offers an optional e-book. With hundreds of guided simulations, animations, video clips, and more, CHEMISTRY & CHEMICAL REACTIVITY, 7e, is more completely integrated with accompanying technology than any other text on the market. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.
  chemistry and chemical reactivity: Chemistry Education Javier García-Martínez, Elena Serrano-Torregrosa, 2015-05-04 Winner of the CHOICE Outstanding Academic Title 2017 Award This comprehensive collection of top-level contributions provides a thorough review of the vibrant field of chemistry education. Highly-experienced chemistry professors and education experts cover the latest developments in chemistry learning and teaching, as well as the pivotal role of chemistry for shaping a more sustainable future. Adopting a practice-oriented approach, the current challenges and opportunities posed by chemistry education are critically discussed, highlighting the pitfalls that can occur in teaching chemistry and how to circumvent them. The main topics discussed include best practices, project-based education, blended learning and the role of technology, including e-learning, and science visualization. Hands-on recommendations on how to optimally implement innovative strategies of teaching chemistry at university and high-school levels make this book an essential resource for anybody interested in either teaching or learning chemistry more effectively, from experience chemistry professors to secondary school teachers, from educators with no formal training in didactics to frustrated chemistry students.
  chemistry and chemical reactivity: Chemical Kinetics Luis Arnaut, 2021-06-22 Chemical Kinetics: From Molecular Structure to Chemical Reactivity, Second Edition, explains how molecular structures change with time. It offers a comprehensive and coherent coverage of the rates of chemical transformations. The book is written for both undergraduate chemistry students, and for the specialist. The newcomer will find the fundamental concepts, the simple experiments, and the underlying theories. For the seasoned specialist, it presents sophisticated experimental and theoretical methods, offering a panorama of time-dependent molecular phenomena connected by a new rationale. The gap between the two is bridged by a logical path that leads the reader from a phenomenological approach of molecular changes, to the formalism of chemical reaction rates, and then to state-of-the-art calculations of rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. In the process, the reader is presented with the details of collision and transition state theories. The coverage includes unimolecular reactions in the gas phase, reactions in solution and reactions on surfaces. - All first edition chapters were revised and most were extended - Features two new chapters, one on Pharmacokinetics and the other on Oscillatory Reactions and Chaos - Includes practical examples, detailed theoretical calculations, and cross-relations between reactions throughout the text to underscore key concepts - The rigor of mathematical description of phenomena is combined with simple and profusely-illustrated concepts - Provides a state-of-the-art presentation on the kinetics of reactions implicated in the most active research fields
  chemistry and chemical reactivity: Structure and Reactivity in Organic Chemistry Mark G. Moloney, 2008-04-28 The jump from an understanding of organic chemistry at lower undergraduate level to that required at postgraduate level or in industry can be difficult. Many advanced textbooks contain a level of detail which can obscure the essential mechanistic framework that unites the huge range of facts of organic chemistry. Understanding this underlying order is essential in any advanced study or application of organic chemistry. Structure and Reactivity in Organic Chemistry aims to bridge that gap. The text opens with a short overview of the way chemists understand chemical structure, and how that understanding is essential in developing a good knowledge of chemical reactivity and mechanism. The remainder of the text presents a mechanistic classification of modern organic chemistry, developed in the context of synthetic organic chemistry and exemplified by reference to stereoselective synthesis and protecting group chemistry. This approach is intended to illustrate the importance and value of a good grasp of organic reaction mechanisms, which is a prerequisite for a broader understanding of organic chemistry. Written by an expert educator with a sound understanding of the needs of different audiences, the subject is presented with clarity and precision, and in a highly practical manner. It is relevant to undergraduates, postgraduates and industrial organic chemists.
  chemistry and chemical reactivity: Reaction Rate Theory and Rare Events Baron Peters, 2017-03-22 Reaction Rate Theory and Rare Events bridges the historical gap between these subjects because the increasingly multidisciplinary nature of scientific research often requires an understanding of both reaction rate theory and the theory of other rare events. The book discusses collision theory, transition state theory, RRKM theory, catalysis, diffusion limited kinetics, mean first passage times, Kramers theory, Grote-Hynes theory, transition path theory, non-adiabatic reactions, electron transfer, and topics from reaction network analysis. It is an essential reference for students, professors and scientists who use reaction rate theory or the theory of rare events. In addition, the book discusses transition state search algorithms, tunneling corrections, transmission coefficients, microkinetic models, kinetic Monte Carlo, transition path sampling, and importance sampling methods. The unified treatment in this book explains why chemical reactions and other rare events, while having many common theoretical foundations, often require very different computational modeling strategies. - Offers an integrated approach to all simulation theories and reaction network analysis, a unique approach not found elsewhere - Gives algorithms in pseudocode for using molecular simulation and computational chemistry methods in studies of rare events - Uses graphics and explicit examples to explain concepts - Includes problem sets developed and tested in a course range from pen-and-paper theoretical problems, to computational exercises
  chemistry and chemical reactivity: Collision Theory and Statistical Theory of Chemical Reactions S. G. Christov, 2012-12-06 Since the discovery of quantum mechanics,more than fifty years ago,the theory of chemical reactivity has taken the first steps of its development. The knowledge of the electronic structure and the properties of atoms and molecules is the basis for an un derstanding of their interactions in the elementary act of any chemical process. The increasing information in this field during the last decades has stimulated the elaboration of the methods for evaluating the potential energy of the reacting systems as well as the creation of new methods for calculation of reaction probabili ties (or cross sections) and rate constants. An exact solution to these fundamental problems of theoretical chemistry based on quan tum mechanics and statistical physics, however, is still impossible even for the simplest chemical reactions. Therefore,different ap proximations have to be used in order to simplify one or the other side of the problem. At present, the basic approach in the theory of chemical reactivity consists in separating the motions of electrons and nu clei by making use of the Born-Oppenheimer adiabatic approximation to obtain electronic energy as an effective potential for nuclear motion. If the potential energy surface is known, one can calculate, in principle, the reaction probability for any given initial state of the system. The reaction rate is then obtained as an average of the reaction probabilities over all possible initial states of the reacting ~artic1es. In the different stages of this calculational scheme additional approximations are usually introduced.
  chemistry and chemical reactivity: Chemical Bonding at Surfaces and Interfaces Anders Nilsson, Lars G.M. Pettersson, Jens Norskov, 2011-08-11 Molecular surface science has made enormous progress in the past 30 years. The development can be characterized by a revolution in fundamental knowledge obtained from simple model systems and by an explosion in the number of experimental techniques. The last 10 years has seen an equally rapid development of quantum mechanical modeling of surface processes using Density Functional Theory (DFT). Chemical Bonding at Surfaces and Interfaces focuses on phenomena and concepts rather than on experimental or theoretical techniques. The aim is to provide the common basis for describing the interaction of atoms and molecules with surfaces and this to be used very broadly in science and technology. The book begins with an overview of structural information on surface adsorbates and discusses the structure of a number of important chemisorption systems. Chapter 2 describes in detail the chemical bond between atoms or molecules and a metal surface in the observed surface structures. A detailed description of experimental information on the dynamics of bond-formation and bond-breaking at surfaces make up Chapter 3. Followed by an in-depth analysis of aspects of heterogeneous catalysis based on the d-band model. In Chapter 5 adsorption and chemistry on the enormously important Si and Ge semiconductor surfaces are covered. In the remaining two Chapters the book moves on from solid-gas interfaces and looks at solid-liquid interface processes. In the final chapter an overview is given of the environmentally important chemical processes occurring on mineral and oxide surfaces in contact with water and electrolytes. - Gives examples of how modern theoretical DFT techniques can be used to design heterogeneous catalysts - This book suits the rapid introduction of methods and concepts from surface science into a broad range of scientific disciplines where the interaction between a solid and the surrounding gas or liquid phase is an essential component - Shows how insight into chemical bonding at surfaces can be applied to a range of scientific problems in heterogeneous catalysis, electrochemistry, environmental science and semiconductor processing - Provides both the fundamental perspective and an overview of chemical bonding in terms of structure, electronic structure and dynamics of bond rearrangements at surfaces
  chemistry and chemical reactivity: Chemistry and Chemical Reactivity, Enhanced Edition John Kotz, Paul Treichel, John Townsend, 2009-02-09 Revised to help students obtain a higher level of understanding of general chemistry concepts, CHEMISTRY & CHEMICAL REACTIVITY, 7th Edition provides the most robust homework/assessment tools ever offered in chemistry. The Enhanced Review Edition combines the text's signature logical organization, macro to micro orientation, and superior art program with new exam preparation sections designed to help students better prepare for multiple chapter examinations. Let's Review sections present study tips, key points lists, and new exam-type questions for multiple chapters grouped according to where most exams occur in the course. The Enhanced Review Edition includes the same integration of media as the standard edition, which includes hundreds of guided simulations, animations, video clips, and a personal tutor. Online Web-based Learning (OWL) is a fully customizable homework system with an optional e-book that maximizes study time and your options for assignments and is available for separate purchase or in a package with your text. Additional more challenging end-of-chapter study questions, which are fully assignable in OWL, give you more choices. And for the student on the go, the new Go Chemistry mini video lectures and flash cards provide the perfect quick review. Quality writing, seamless technology integration, and a rich ancillary package remain the hallmarks of the text. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.
  chemistry and chemical reactivity: Preview Edition: Chemistry/Chemical Reactivity 4e Jack C Kotz, John C. Kotz, Paul M Treichel, 1998-02 Quality writing, seamless technology integration, and a rich ancillary package are hallmarks of John C. Kotz and Paul M. Treichel, Jr.'s CHEMISTRY AND CHEMICAL REACTIVITY. Now thoroughly revised and enhanced, the fifth edition of this best-selling text will bring students to a new level of understanding and appreciation for chemistry's vital role in their lives. By emphasizing the close interrelationship of the macroscopic, symbolic, and particulate levels of chemistry, Kotz and Treichel provide an important organizing principle that carries throughout the book. The text's significantly revised art program reveals these three levels in engaging detail. This new art program is fully integrated with CHEMISTRY AND CHEMICAL REACTIVITY'S unparalleled CD-ROM, GENERAL CHEMISTRY INTERACTIVE, VERSION 3.0. With hundreds of guided simulations, animations, and video clips, as well as new Intelligent Tutors that guide students step-by-step through problems, GENERAL CHEMISTRY INTERACTIVE is the benchmark learning tool by which all others are measured--and it is included with every new copy of the text.
  chemistry and chemical reactivity: Chemistry Theodore L. Brown, 2007 Intended for first year Chemistry majors and non-majors, this book teaches students the concepts and skills for understanding chemistry, and contains content related to Organic Chemistry. It also provides the information students need for learning, skill development, reference and test preparation.
  chemistry and chemical reactivity: Chemistry Bruce Averill, Patricia Eldredge, 2007 Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
  chemistry and chemical reactivity: Chemistry Peter G. Mahaffy, John C. Kotz, John McMurry, R. B Bucat, Roy Tasker, Paul Treichel, Gabriela C. Weaver, 2014-03-31 Taking an evidence-first big picture approach, Chemistry: Human Activity, Chemical Reactivity encourages students to think like a chemist, develop critical understanding of what chemistry is, why it is important and how chemists arrive at their discoveries. Flipping the traditional model of presenting facts and building to applications, this text begins with contexts that are real-life and matter to students - from doping in sports, to the chemistry behind the treads of wall-climbing robots. Informed by the latest chemical education research, Chemistry: Human Activity, Chemical Reactivity presents chemistry as the exciting, developing human activity that it is, rather than a body of facts, theories, and skills handed down from the past. Along with the innovative MindTap Reader and OWLv2 learning platform, this text uses unique case studies and critically acclaimed interactive e-resources to help students learn chemistry and how it is helping to address global challenges of the 21st century.
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